Interesting question and for some reason I’ve been wondering about that so did a little research. More confused than ever now though.
Turns out that the southern hemisphere, like New Zealand gets 50% more UV than the equivalent northern latitudes, so they’re very interested in u.v. So Lincoln University in NZ is doing some studies right now on exactly that issue. And since I was kind of curious about it, I came across some of their work. They issued a press release a couple weeks ago on some of their work, stating:
"Specifically, UV causes accumulation of polyphenols (compounds that absorb the UV radiation and therefore protect the plant) in the grape skins and this may lead to changes in the properties of the wine, such as ageing and mouth feel. "
Then there’s this from another study, I think it’s also from NZ and possibly even from Lincoln, but saved it as Word so I don’t know for sure:
However, Hashizume & Samuta (1999) found light exposure had two opposite effects on the concentration of methoxypyrazines. Prior to veraison, IBMP concentration within berries was enhanced by berry light exposure; after veraison IPMP concentration decreased with exposure. They suggested that the production of methoxypyrazines might be closely related to the developmental stage of grapes, such that in the early stages the amount formed biologically exceed that degraded but in the later stages decomposition exceeded formation.
Increased levels of u.v. exposure increase the concentrations of quercetin in berries which makes this compound an excellent indicator of light exposure level . . . The flavour of quercetin has been characterised as generally being bitter and astringent. . . tasters described it as . . .sweet, sour, bitter, metallic, musty/dirty, viscosity, burn/alcohol, mouth coating, numbness/tingling, astringency and throat tightness. . . .Price et al. (1995) believe that quercetin can have powerful effects on red wine quality through its ability to co-pigment with other wine constituents and possess the potential to change, boost and stabilise anthocyanins. . .
(FYI - IBMP is 2-Methoxy-3-isobutylpyrazine, which is largely responsible for the bell-pepper flavors in the cab family and sauvignon blanc)
There was some study I remember where they used u.v. to irradiate wine with ladybug taint, because the bugs also add a lot of the bell pepper flavor to wine. Farmers have been trying to introduce them to eat aphids. They brought some from Asia and finally a colony took root in Lousiana and it’s moved west. We never learn because those ladybugs are stinkbugs and now they’re screwing the wineries. So people tried irradiating the tainted wine with u.v. but it didn’t seem to help. However, it turns out that the orange ladybugs have 10 times as much as their yellow cousins, but it’s hard to kill just one color of bug.
So I guess that the u.v. has a lot of influence on some things but it’s far more complicated than simply exposing a grape or not. It’s effects are also very much temperature-dependent. Sigh. Too much to learn.